Tamil Nadu Factories Rules 1950

R.62C

SCHEDULE 5

 

FORMAT OF A MATERIAL SAFETY DATA SHEET

See rules 3 (2) and (3)

 

1.             IDENTITY OF MATERIAL

Product Name

Chemical Designation

Trade Name

Synonyms

Formula

Label: Category Class

 

CAS Number

UN Number

Regulated Identification

Shipping Name Codes / Label

HAZCHEM Code :

Hazardous waste Identification Number

 

Hazardous Ingredients

CAS Number

1.

 

2.

 

3.

 

4.

 

 

 

2.             PHYSICAL AND CHEMICAL PROPERTIES           

Physical State (Gas-, Liquid-, Solid-)

Boiling point in degree C

Vapour pressure at 35 degree
C                                        

mm Hg.

Appearance

Melting / Freezing point in degree C

Evaporation rate at 30 degree C

Odour

Vapour Density (air-1)

Solubility in water at 30 degree C

Others (Corrosivity, etc.,)

Specific Gravity
(Water-1)

PH

 

3.             FIRE AND EXPLOSIVE HAZARDS DATA

Explosion /
Flammability

Flash Point
(deg.) C

LEL

        %

Autoignition Temperature degree C

Flash Point (deg.) C

LEL

%

TDG Flammability (Classification)

 

4.             REACTIVE HAZARDS

Impact (hazardous Combustion products)

Stability to Static Discharge (hazardous decomposition products)

Reactivity (Conditions to avoid)

 

 

Hazardous

May / May not

(Conditions to avoid)

Polymerisation

Occur

 

Incompatibility

(Materials to avoid)

 

 

 

5.             HEALTH HAZARD DATA

Routes of Entry :

(Inhalation, skin, mucus membranes and eye contact and ingestion).

Effects of Exposure / Symptoms :

LD  50 (in rat) (Orally or percutaneous absorption (mg/kg body Weight)

LC 50 (in rat) (mg / 1) / 4 hours.

Permissible Exposure Limit (PEL)

PPM mg / cu.sm

Short term ppm mg / cu.m.

Exposure Limit (STEL)

Threshold Limit Value (TLV) of  ACGIH

PPM mg / cu.m

Odour Threshold ppm mg/cu.m.

Emergency Treatment :

 

6.             HAZARD SPECIFICATION

N E P A  HAZARD

Signal

Health

Flammability

Stability

Special

 

 

 

 

 

Known Hazards :

Combustible Liquid

Water Reactive Material

Irritant

Flammable Material

Oxidiser

Sensitizer

Pyrophoric Material

Organic peroxide

Carcinogen

Explosive Material

Corresive Material

Mutagen

Unstable Material

Compressed Gas

Other (Specify)

 

7.      SAFE USAGE DATA

Ventilation

General / Mechanical 

Local Exhaust

 

Protective

Equipment

Required

Eyes (Specify)

Respiratory (Specify)

Gloves (Specify)

Clothing (Specify)

Others (Specify)

Precautions

Handling & Storage

Others (Specify)

 


8.      EMERGENCY RESPONSE DATA

 

Fire

Fire Extinguishing Media

Special Procedures

Unusual Hazards

Exposure (inhalation, skin
and eye contact, ingestion)

First Aid Measures

Spills

Steps to be taken

Waste Disposal Method

 

 

9.             ADDITIONAL INFORMATION

 

10.         SOURCES USED

         Reference to books, journals, etc.,

 

12.         MANUFACTURER / SUPPLIER DATE

 

Firm’s Name

Standard packing

Mailing Address

 

Telephone Number

Other

Telex Number

Other

Telegraphic Address

 

Contact person in Emergency

Emergency Telephone in Transit areas.

 

Acronyms and Glossary of terms:

CAS: Chemical Abstract Service Registration Number

UN Number: United Nations Number.

HAZCHEM Code: Emergency Action Code (EAC), allocated by the Joint Committee of Fire Brigade Operations, U.K.

TDG Flammability: Transport of Dangerous Goods –Flammability Classification by United Nations.

NEPA: Nation Fire Protection Association USA.

LD 50 and LC 50 represent the dose in mg / kg / of body weight and the concentration in mg / 1 for 4 hours having lethal effect on 50% of the animals (rats) treated.

PEL: Permissible Exposure Limit as laid down in the statutes.

TVL : Threshold Limit Value as laid down by the American Conference of Government industrial Hygienists (ACGIH) USA.

STEL : Short Term Exposure Limit as laid down in the statutes or by the ACGIH.

GUIDELINES:

All effects should be made to fill in all the columns. No column should be left blank. In case certain information is applicable or available, N / App. or N / Av. sign should be used.