Gujarat Factories Rules

 

SCHEDULE 3

(Rules 68-J 1(a)(iii), 1(e) and (5)(1) and (b), 6(1)

LIST OF HAZARDOUS CHEMICALS FOR APPLICATION OF
SUB-RULES 5 AND 7 TO 13

(a)     The quantities set out below relate to each installation or group of installations belonging to the same occupier where the distance between the installations is not sufficient to avoid in foreseeable circumstances, any aggravation of major accident hazards. These quantities apply in any case to each group of installations belonging to the same occupier where the distance between the installations is less than 500 metres.

(b)    For the purpose of determining the quantity of a hazardous chemical in an industrial installation, account shall also be taken of any hazardous chemical which is:

(i)      in that part of any pipeline under the control of the occupier having control of the site, which is within 500 metres of that site and connected to it;

(ii)     at any other site under the control of the same occupier any part of the boundary of which is within 500 metres of the said site ; and

(c)     in any vehicle, vessel, aircraft or hovercraft under the control of the same occupier which is used for storage purpose either at the site or within 500 metres of it.

but no account shall be taken of any hazardous chemical which is in a vehicle, vessel, aircraft or hovercraft used for transporting it.

PART 1 - NAMED CHEMICALS

Sr.
No.

Chemical

Quantity

 

CAS Number

For application of sub-rules (4) (6) to (8) and 12

For Application of sub-rules 9 to 11

(1)

(2)

(3)

(4)

(5)

Group 1 - Toxic Chemicals

1.

Aldcarb

100 kg.

 

116-06-3

2.

4-Aminidipheny

1 kg.

 

92-67-1

3.

Amltom

1 kg.

 

78-53-5

4.

Anabasine

100 kg.

 

494-52-0

5.

Arsenic pentoxide

Arsenic (v) acid & salts

500 kg

 

 

6.

Arsenic trioxide Arsenious

(iii) acid & salts

100 kg.

 

 

7.

Irsine (Arsine Arsenic Hydride)

10 kg.

 

7784-42-1

8.

Azinphos-ethy

100 kg.

 

2642-71-9

9.

Azinphos-methy

100 kg.

 

86-50-0

10.

Benzidine

1 kg.

 

92-87-5

11.

Benzkine Salts

1 kg.

 

 

12.

Beryllium (powders, compounds)

10 kg.

 

 

13.

Bis (2-chioroethyl) sulphide

1 kg.

 

505-60-2

14.

Bis (chioromethyl) ether

1 kg.

 

542-88-1

15.

Carbofuran

100 kg.

 

1563-66-2

16.

Carbophenthion

100 kg.

 

786-19-6

17.

Chlorfenvnphos

100 kg.

 

470-90-6

18.

4-(chiorofomyl) Morpholine

1 kg.

 

15159-40-7

19.

Chotomethyl ether

1 kg.

 

107-30-2

20.

Cobalt metal, oxides, carbonates, sulphides, as powders

1 t

 

 

21.

Crimidine

100 kg.

 

535-89-7

22.

Cynathoate

100 kg.

 

3734-95-0

23.

Cyloheximide

100 kg.

 

66-81-9

24.

Demeton

100 kg.

 

8065-48-3

25.

Diallfos

100 kg.

 

10311-84-9

26.

co-diethyl
S-ethyisulphnylmethy phosphorthloate

100 kg.

 

2588-05-8

27.

co-Doethyl
S-ethyisulphonylmethyl
phosphorthloate

100 kg.

 

2588-06-9

28.

co-Diethyl
S-ethylthiomehys
phosphorodithithioate

100 kg.

 

2600-69-3

29.

co-Diethyl
S-isoprophyithiomethyl
phosphorodithioate

100 kg.

 

78-52-4

30.

co-Diethyl
S-propylthiomethyl
phosphorothioate

100 kg.

 

3309-68-0

31.

Dimefox

100 kg.

 

115-26-4

32.

Dimethyyl carbamoyl chloride

1 kg.

 

79-44-7

33.

Dimethylnitosamine

1 kg.

 

62-75-9

34.

Dimethyl
phosphoramidocyanide
acid

1 t

 

63917-41-9

35.

diphacinone

100 kg.

 

82-66-6

36.

Disulfoton

100 kg.

 

298-04-4

37.

EPN

100 kg.

 

2104-64-5

38.

Ethion

100 kg.

 

563-12-2

39.

Fensulfothion

100 kg.

 

115-90-2

40.

Fluenetil

100 kg.

 

4301-50-2

41.

Fluoroacetic acid

1 kg.

 

144-49-0

42.

Fluorocatle acid, salts

1 kg.

 

 

43.

Fluoroacetic acid, esters

1 kg.

 

 

44.

Fluorocacetic acid,
amides

1 kg.

 

 

45.

4-Flourobutyric acid

1 kg.

 

462-23-7

46.

4-Flurobutyric acid, salts

1 kg.

 

 

47.

4-Fluorobutyric esters

1 kg.

 

 

48.

4-Fluorobutyric acid, amides

1 kg.

 

 

49.

4-Fluorocrotonic acid

1 kg.

 

37759-72-1

50.

4-Fluorocronotic acid, salts

1 kg.

 

 

51.

4-Fluorocrotonic esters

1 kg.

 

 

52.

4-Fluorocrotnic, amides

1 kg.

 

 

53.

4-fluoro-2-hydroxy-butyric acid

1 kg.

 

 

54.

4-fluoro-2-hydroxbutyric acid, salts

1 kg.

 

 

55.

4-fluoro-2-hydroxy-butryric acid, esters

1 kg.

 

 

56.

4-fluoro-2-hydroxy-butryric acid, amides

1 kg.

 

 

57.

Glycolonitrile (hydroxvacetonitrille)

100 kg.

 

107-16-4

58.

1,2,3,7,8,9,- Hexachiorodibenzo p-dioxin

100 kg.

 

19408-74-3

59.

Hexamethyipho sphoramide sphoramids

1 kg.

 

680-31-9

60.

Hydrogen selenid

10 kg.

 

7783-07-5

61.

Isobenzan

100 kg.

 

297-78-9

62.

Isodrin

100 kg.

 

465-73-6

63.

Juglone
(5-Hydroxynaphthalene-1,4-dione

100 kg.

 

481-39-0

64.

4,4’-Methylenebls (2-chloroaniline)

10 kg.

 

101-14-4

65.

Methy/Isocyanate

150 kg.

150 kg.

624-83-9

66.

Mevinphose

100 kg.

 

7786-34-7

67.

2-Naphhthylamine

1 kg.

 

91-59-8

68.

Nickel metal, oxides, carbonates, sulphide, as powders

1 t

 

 

69.

Nickel tetracarbony

10 kg.

 

13463-39-3

70.

Oxydisulfoton

100 kg.

 

2497-07-6

71.

Oxygen diffuoride

10 kg.

 

7783-41-7

72.

Paraxon (diethyl) 4-nitrophenyl (Phosphate)

100 kg.

 

311-45-5

73.

Parathion

100 kg.

 

56-38-2

74.

Pacathion-methyl

100 kg.

 

298-00-0

75.

Pentaborane

100 kg.

 

19624-22-7

76.

Phorate

100 kg.

 

298-02-2

77.

Phosacetion

100 kg.

 

4104-14-7

78.

Phosgene (cartbony) chloride

750 kg.

750 kg.

75-44-5

79.

Phosphamidon

100 kg.

 

13171-21-6

80.

Phosphine (Hydrogen phosphide)

100 kg.

 

7803-51-2

81.

Promurit (1-(3,4- Dichorophenyl)- 3-triazenethio cariboxaamide)

100 kg.

 

5836-73-7

82.

1,3-Propanesuiltone

1 kg.

 

1120-71-4

83.

1-Propen-2 chioro-1, 3-diol, diacetate

10 kg.

 

10118-72-6

84.

pyrazoxon

100 kg.

 

108-34-9

85.

Seleniumhexaffuoride

10 kg.

 

7783-79-1

86.

Sodium selenite

100 kg.

 

10102-18-8

87.

Stabine (Antimony hydride)

100 kg.

 

7803-52-3

88.

Sulfotop

100 kg.

 

3689-24-5

89.

Sulphur dichloride

1 t

 

10545-99-0

90.

Tellurium hexafluoride

100 kg.

 

7783-80-4

91.

TEPP

100 kg.

 

107-49-3

92.

2,3,7,8- ‘Tetrachlorodibenzo
P-dioxin (TcDD)

1 kg.

 

1746-01-6

93.

Tetramethylenedisul-photetramine

1 kg.

 

80-12-6

94.

Thionazin

100 kg.

 

297-97-2

95.

Tirpate (2,4-Dimethyl 1,3-dithiolane
2-carboxaldehyde
o-methyl carbomoyloxime)

100 kg.

 

26419-73-8

96.

Trichlormethane sulphenyl chloride

100 kg.

 

594-42-3

97.

1-Tri(cyclohexyl) stannyl-1G-1,2,4-triazole

100 kg.

 

41083-11-8

98.

triethienmelamine

10 kg.

 

51-18-3

99.

Wartarin

100 kg.

 

81-81-2

Group-2 - Toxic Chemicals
(Quantity 1 tonne)

100.

Acentone cyanohydrain (2-Cynopropan-2-01)

200 t

 

75-86-5

101.

Acroieln (2-Propenal)

20 t

 

107-02-8

102.

Acrylonitrelle

20 t

200 t

107-13-1

103.

Allyl alcohol (2-Propen-1-01)

200 t

 

107-18-6

104.

Allylaine

200 t

 

107-11-9

105.

Ammonia

50 t

500 t

7664-41-7

106.

Bromine

40 t

 

7726-95-6

107.

Carbon disulphide

20 t

200 t

75-15-0

108.

Chlorife

10 t

25 t

7782-50-5

109.

Diphyenl mothane di-isocyanate (MD1)

20 t

 

101-68-8

110.

Ethylene dibromide (1,2-Dibromomethane)

5 t

 

106-93-4

111.

Ethyienelmine

50 t

 

151-56-4

112.

Formaldehyde (concentration = 90%)

5 t

 

50-00-0

113.

Hydrogen chloride (liquefied gas)

25 t

250 t

7647-01-0

114.

Hydrogen Cyanide

5 t

20 t

74-90-8

115.

Hydrogen Fluoride

5 t

50 t

7664-39-3

116.

Hydrogen sulphide

5 t

50 t

7783-06-4

117.

Methyl bromide (Bromomethane)

20 t

 

74-83-9

118.

Nitrogen oxides

50 t

 

11104-93-1

119.

Propyleneimine

50 t

 

75-55-8

120.

Sulphur dioxide

20 t

250 t

7446-09-5

121.

Sulphur trioxide

15 t

75 t

7446-11-9

122.

Tetraethyl lead

5 t

 

78-00-2

123.

Tetramethyl lead

5 t

 

75-74-1

124.

Toluene di-isocyanate (TD1)

10 t

 

584-84-9

Group 3–Highly Reactive Chemicals

125.

Acetylene (ethyne)

5 t

 

74-86-2

126.

a.  Ammonium nitrate (1)

b.    Ammonium nitrate in the form of fertilizer (2)

350 t

1,250 t

2500 t

6484-52-2

127.

2,2 Bis (tert-butyl peroxy) butane (concentration >=70%)

5 t

 

2167-23-9

128.

1,1 Bis (tert-butyl peroxy) cyclohexane (concentration>=80%

5 t

 

3006-86-8

129.

Tert-Butyl peroxyacetate (concentration>=70%)

5 t

 

107-71-1

130.

Tert-Butyl peroxysobutyrate (concentration>=80%)

5 t

 

109-13-7

131.

Tert-Butyl peroxyisopropyl carbonate (concentration>=80%)

5 t

 

2372-21-6

132.

Tert-Butyl peroxymaleate (concentration>=80%)

5 t

 

1931-62-0

133.

Tert-Butyl peroxypivalate (concentration>=77%)

50 t

 

927-07-1

134.

Dibenzyl peroxydicarbinate (concentration>=90%)

5 t

 

2144-45-8

135.

Did-sec-butyl peroxdicarbonate (concentration>=80%)

5 t

 

19910-65-7

136.

Diethyl Peroxydicarbonate (concentration>=30%)

50 t

 

14666-78-5

137.

2,2-Dihydroperoxyoropana (concentration>=30%)

5 t

 

2614-76-8

138.

Dl-Isobutryl peroxide (concentration>=50%)

50 t

 

3437-84-1

139.

D1-n-propyl peroxydlcarbonate (concentration>=80%)

5 t

 

16066-38-9

140.

Ethylene oxide

5 t

50 t

75-21-8

141.

Ethyl nitrate

50 t

 

625-58-1

142.

3,3,6,6,9,9-Hexamethyl - 1,2,4,5- tetroxacyclonane (concentration>=75%)

50 t

 

22397-33-7

143.

Hydrogen

2 t

50 t

1333-74-0

144.

Liquid oxygen

200 t

 

7782-44-7

145.

Methyl ethyl ketone Peroxide (concentration>=60%)

5 t

 

1338-23-4

146.

Methyl isobutyl ketone peroxide (concentration>=60%)

50 t

 

37206-20-5

147.

Peracetic acid (concentration>=60%)

50 t

 

79-21-0

148.

Propylene oxide

5 t

 

75-56-9

149.

Sodium chlorate

 

25 t

 

7775-09-9

Group 4- Explosive Chemicals

150.

Barium azide

50 t

 

18810-58-7

151.

151-Bis (2,4,6-trinito phemy) amine

50 t

 

131-73-7

152.

Chiorotrinitrobenzene

50 t

 

28260-61-9

153.

Cellulose nitrate (containing) >12.6% nitrogen)

50 t

 

9004-70-0

154.

Cyclotetramethylene tetranitramine

50 t

 

2691-41-0

155.

Cyclotrimethylenetri nitroamine

50 t

 

121-82-4

156.

Diazodinitrophenol

10 t

 

7008-81-3

157.

Diethylene glycol dinitrate

10 t

 

693-21-0

158.

Dinitrophenol, salts

50 t

 

 

159.

Ethylene glycol dinitrate

10 t

 

628-96-6

160.

1-Guanyl-4-nitrosamineoguanyl -1- tetrazene

10 t

 

109-27-3

161.

2.2’, 4.4’,
6.6’- Hexanitrostilbene

50 t

 

20062-22-0

162.

Hydrazine nitrate

50 t

 

13464-97-6

163.

Lead azide

50 t

 

13424-46-9

164.

Lead styphnate (lead 2,4,
6-trinitroresorcinoxide)

50 t

 

15245-44-0

165.

Mercury fulminate

10 t

 

628-86-4

166.

N-Methyl-N 2,4,6 Tetranitroanline

50 t

 

479-45-8

167.

Nitrogylcerine

10 t

10 t

55-63-0

168.

Pentacrythritol tetranitrate

50 t

 

78-11-5

169.

Picric acid-2,4,6 (Trinitrophenol)

50 t

 

88-89-1

170.

Sodium pieramate

50 t

 

831-52-7

171.

Styphnic acid (2,4,6-Trinitroresorcinol)

50 t

 

82-71-3

172.

1,3,5- Triamino-2,4,6-Trinitrobenezene

50 t

 

3058-38-6

173.

Trinitroaniline

50 t

 

26952-42-1

174.

2,4,6-Trinitroanisole

50 t

 

606-35-9

175.

Trinitrobenzene

50 t

 

25377-32-6

176.

Trinitrobenzoic acid

50 t

 

35860-50-5

177.

Trinitrocresol

50 t

 

28905-71-7

178.

2,4,6-Trinitrophenetole

50 t

 

4732-14-3

179.

2,4,6-Trinitrotoluene

50 t

50 t

118-96-7

PART II - CLASSES OF CHEMICALS NOT SPECIFICALLY NAMED IN PART I

Sr. No.

Classes of Chemicals

Quantity

For application of Sub-rules (4), (6) to (8) & (12)

For application of Sub-rules (9) to 11

(1)

(2)

(3)

(4)

Group-5: Flammable Chemicals

1.

Flammable Gases:
Chemicals which in gaseous state at normal pressure and mixed with air become flammable and the boiling point of which at normal pressure is 20 degreed C or below

15 t

200 t

2.

Highly flammable liquids:
Chemicals which have a flash point lower than 23 degree C and the boiling point of which at normal pressure is above 20 degree C;

1000 t

50000 t

3.

Flammable liquids:
Chemicals which have a flash point lower than 65 degree C and which remain liquid under pressure, where particular processing conditions, such as high pressure and high temperature, may create major accident hazards.

25 t

200 t

 

Footnotes:

1.       This applies to ammonium nitrate and mixture of ammonium nitrate where the nitrogen content derived from the ammonium nitrate is greater than 20% by weight and aqucous solutions of ammonium nitrate where the concentration of ammonium nitrate is greater than 90% by weight.

2.       This applies to straight ammonium fertilisers and to compound fertilisers where the nitrogen content derived from the ammonium nitrate is greater than 28% by weight (a compound fertiliser contains ammonium nitrate together with phosphate and/or potash).

 

CAS number (Chemical Abstracts Service Number) means the number assigned to the chemical by the Chemical Abstracts Service.